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Decaffeinated Coffee & Methyl Chloride–Best & Worst Decaf Coffee Brands

Mamavation » Blog » Food | Mamavation » Decaffeinated Coffee & Methyl Chloride–Best & Worst Decaf Coffee Brands
filling up a cup of coffee at a cafe

February 12, 2020 //  by Leah Segedie

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When you find out you are pregnant or just get the jitters when you drink coffee, decaffeinated coffee may be what you reach for. But watch out! The Clean Label Project recently commissioned a lab study on all the most popular decaffeinated coffee brands and there are big differences when it comes to toxins appearing in the brew. You’ve trusted Mamavation to bring you topics like best & worst creamers, best & worst coffee, and best & worst collagen, now join us for all the details of which decaffeinated coffee brands are least likely to deliver toxins with your cup of joe!

Disclosure: This post contains affiliate links. 

Coffee beans in an old wooden scoop

Table of Contents

  • Decaf Coffee Is Recommended for Those With Heart Conditions, High Blood Pressure & Pregnant Women
  • Americans & Caffeine Dependence
  • Some Types of Decaffeinated Coffee Are Problematic Based On How They are Processed
  • Methyl Chloride–Contamination in Decaf Coffee
  • Methyl Chloride Should Be Avoided During Pregnancy
  • Clean Label Project Laboratory Study of Decaffeinated Coffee Products
  • Mamavation’s Investigation of Decaffeinated Coffee Brands
    • Bad Decaffeinated Coffee Brands
    • Better Decaffeinated Coffee Brands
    • Best Decaffeinated Coffee Brands

Decaf Coffee Is Recommended for Those With Heart Conditions, High Blood Pressure & Pregnant Women

It’s been recommended that you cut down on caffeine if you fall somewhere in one of these categories:

  • have heart disease and/or high blood pressure
  • pregnant women
  • have depression, anxiety, or sleeping conditions
  • have heartburn, stomach acid, or chronic headaches

About 647,000 Americans die every year of heart disease, making that statistic 1 in every 4 deaths. People facing heart disease need to lower their consumption of caffeine to no more than 3 cups per day.

Meanwhile, pregnant women need to be mindful that caffeine is a stimulant that can pass through the placenta, so it’s recommended they also switch to decaf.  However, decaf still has caffeine inside. To put it in perspective, 5-10 cups of decaf coffee have similar amounts of caffeine as 2 cups of regular coffee.

For those who suffer from depression, anxiety, or sleeping problems, it would be wise to consider the switch to decaf, or even the reduction of your caffeine intake. You know that jittery feeling you get from drinking too much coffee? Well, that’s a similar feeling to a panic attack so why willingly bring on those symptoms? Unfortunately, caffeine can aggravate anxiety symptoms.

And it’s debatable whether the caffeine protects you from other contaminants inside coffee. Researchers have wondered whether any of coffee’s healthful compounds are lost along with the caffeine making decaf coffee possibly the least healthy of drinks.

As well, if you have heartburn problems, stomach ulcers, chronic headaches, or are pregnant, a decaf cup of coffee might be a better choice.

Decaffeinated Coffee in a bag spilled on the floor

Americans & Caffeine Dependence

Most American adults consume more than 280 mg of caffeine per day, which is high enough to create caffeine dependence and withdrawal symptoms if you suddenly stop consuming caffeine. The more caffeine you consume, the more likely you will experience withdrawal symptoms when you finally quit. Because caffeine is a stimulant that increases heart rate, blood pressure, and the stress hormones cortisol and epinephrine, the most commonly reported symptoms include:

  • headaches (less than 3 cups can reduce cerebral blood flow by as much as 27%)
  • fatigue
  • drowsiness
  • difficulty concentrating
  • irritability
  • anxiety
  • flu-like symptoms
  • impairment in psychomotor, vigilance & cognitive performances

Caffeine is found in so many products, it may be hard to estimate how much you are getting per day. When just 100 mg per day is enough to create withdrawal symptoms, it’s no wonder Americans are so dependent on caffeine. Here are examples of how much you are getting per day.

  • Brewed coffee: 70 to 200 mg caffeine
  • Black tea: 40 to 120 mg caffeine
  • Flavored & green teas & soft drinks: 15 to 71 mg caffeine
  • Chocolate bars: 9 to 31 mg caffeine
  • Coffee-flavored ice cream: 30 to 84 mg caffeine

Freshly roasted decaf coffee

Some Types of Decaffeinated Coffee Are Problematic Based On How They are Processed

Decaffeinated coffee can be problematic depending on the way the caffeine is stripped from the bean and what solvents and chemicals are used in that process. There are many ways to extract the caffeine, but not all are recommended.

All beans start green and are then soaked or steamed until caffeine is dissolved. Then the caffeine is extracted using one of the following methods:

  • Solvent Based: soaking beans in a chemical solvent– methylene chloride and/or ethyl acetate (very common)
  • Solvent Based: soaking beans in a chemical solvent–some companies are using legacy toxic chemicals benzene, trichloroethylene (TCE), and/or dichloromethane (pretty rare)
  • Solvent Based: using liquid carbon dioxide (CO2)
  • Non-Solvent: relies on water, time & temperature, but sometimes has less flavor
  • Non-Solvent: uses “Swiss Water Processing” (favored)

Benzene, trichloroethylene (TCE) or dichloromethane are rarely used. However, when inhaled, some of these chemicals contaminants can cause drowsiness, dizziness & headaches as well as eye, skin & respiratory tract irritation. Over the long term under certain conditions, benzene is linked to cancer, blood disorders, and development issues in children.

Decaffeinated Coffee & Methyl Chloride--Best & Worst Decaf Coffee in an armenian silver canister

Methyl Chloride–Contamination in Decaf Coffee

The most common contaminant to find in decaf coffee is methyl chloride, a paint thinner chemical. It’s the same colorless volatile liquid chlorinated hydrocarbons commonly used as a solvent in paint thinners. In animal studies, this chemical was linked to cancer of the liver and other organs. The FDA’s official stance is it’s carcinogenic to humans when inhaled and may be carcinogenic to humans.

Consumers are exposed through inhalation or absorption through the skin. Symptoms can be instant dizziness, loss of consciousness, and irritation of the nose and throat. Acute exposure can cause death.

In 2019, The U.S. Environmental Protection Agency banned its consumer use after controversial deaths linked to its use inside paint thinners and a consumer campaign lead by Safer Chemicals Healthy Families lead to bans among retailers like Walmart, Home Depot & Lowes.

Decaffeinated Coffee & Methyl Chloride--Best & Worst Decaf Coffee Brands

Methyl Chloride Should Be Avoided During Pregnancy

The State of California recently added Methyl Chloride to its Prop. 65 List of Carcinogens & Reproductive Toxicants, but specifically added that it’s the ability to pass through the placenta was particularly bad.

In addition, methyl chloride can also persist in the air for over 500 days, so it’s best not to bring it into the home if you are pregnant or planning on getting pregnant.

Heart shape made from coffee beans with a spoon and cup of coffee on hessian spelling I love coffee

Clean Label Project Laboratory Study of Decaffeinated Coffee Products

Clean Label Project tested the top 25 decaffeinated coffee brands on Amazon.com & Walmart.com. Each sample was prepared by adding 0.5 grams of ground coffee to a vial along with 5ml of water, stirring a bar, and testing using Gas Chromatography Mass Spectroscopy with Purge and Trap (GSMS/P&T). The level of qualification (LOQ) was 50 ppb (parts per billion).

Many brands tested positive for methyl chloride, including some of the most popular brands. When it comes to benchmarking, the Clean Label Project ranked the levels.  Anything above 90 ppb (parts per billion) were ranked bad, anything between 50-89 ppb was rated better, and anything at non-detect levels of below 50 ppb rated best.

Several organic decaf brands tested below the detection level, so we felt comfortable adding more organic decaf brands as options in the best categories.

Closeup of Female holding coffee with heart symbol

Mamavation’s Investigation of Decaffeinated Coffee Brands

Mamavation took the laboratory results of decaffeinated coffee brands from the Clean Label Project and combined that with our knowledge of the organic standards for decaffeinated coffee. To create this list, we combined the two to offer you more options for “best” brands. Each category below uses the benchmarking established by the Clean Label Project to evaluate levels of methyl chloride.

Bad Decaffeinated Coffee Brands

These brands had more than 90 ppb (parts per billion) of methyl chloride detected in their product.

  • AmazonFresh
  • Cafe Bustelo
  • Gevalia Kaffe
  • Great Value
  • Green Mountain Coffee Roasters
  • Kroger

Coffee cup and beans on a white background

Better Decaffeinated Coffee Brands

These brands range from 50 to 89 ppb (parts per billion) of methyl chloride in their products.

  • Kirkland Signature Decaf Coffee
  • Maxwell House Decaf Coffee
  • Peet’s Coffee Decaf Coffee
  • Seattle’s Best Decaf Coffee

Group of friends making a toast with coffee

Best Decaffeinated Coffee Brands

These brands were less than 50 ppb (parts per billion) of methyl chloride in their products. We would highly recommend organic products because the processing of those beans prohibits the use of methyl chloride. With this confirmation in testing, we’ve added more organic decaffeinated coffee brands for you to choose from. They don’t use methyl chloride and there doesn’t seem to be contamination in the industry.

  • 365 Organic Everyday Value Decaf Coffee
  • Allegro Organic Decaf Coffee
  • Archer Farms Decaf Coffee
  • Caribou Coffee Decaf Coffee
  • Community Coffee Decaf Coffee
  • Dazbog Decaf Coffee
  • Dunkin’ Donuts Original Decaf Coffee
  • Folgers Decaf Coffee 
  • High Ground Organic Instant Decaf Coffee
  • Illy Decaf Coffee Ground
  • Jeremiah’s Pick Organic Decaf Coffee
  • Kicking Horse Decaf Coffee
  • Kofiahana Organic Low-Acid Decaf Coffee
  • Mayorga Organics Decaf Coffee Beans
  • Mommee Coffee Low Acid Organic Decaf Coffee
  • Mount Hagen Instant Organic Decaf Coffee
  • Nescafe Decaf Instant Coffee
  • No Fun Joe Decaf Coffee 
  • Peak Performance High Altitude Decaf Coffee
  • Subtle Earth Organic Decaf Coffee
  • Starbucks Decaf Coffee
  • The Organic Coffee Co. Decaf Gorilla Coffee
  • Tim Hortons Decaf Coffee
  • Wicked Joe Organic Coffee Decaf Coffee

Pin it!

Decaffeinated Coffee & Methyl Chloride--Best & Worst Decaf Coffee Brands 2

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Reader Interactions

Comments

  1. Vince

    May 3, 2024 at 6:06 am

    This is from 2020. As of 2022, Pete’s uses water process and should not have methylene chloride. Starbucks does use it, so the results here are surprising.

    Reply
    • E

      December 4, 2024 at 4:52 pm

      Community Coffee uses methylene chloride also.

      Reply
  2. Janet Peterson

    April 18, 2024 at 7:58 am

    How about Timothy’s decaf for in Keurig use?

    Reply
    • Larry

      April 11, 2025 at 5:34 pm

      Is Timothy’s decaf produced with meth cl. If so what is the ppb

      Reply
  3. Jeannie

    April 17, 2024 at 4:33 am

    This article states fda banned methylene chloride in the 70’s.
    https://www.streetdirectory.com/etoday/green-mountain-coffee-decaf-cpwpeu.html#:~:text=Chemically%20removing%20caffeine%20from%20unroasted,and%20is%20then%20rinsed%20away

    Reply
  4. Harriet

    March 9, 2024 at 9:26 am

    Glad to see that Folger’s is considered safe. I assume that this is true of their instant coffee as well as their brewed.

    Reply
  5. Anonymous

    March 2, 2024 at 6:26 am

    Is the Kirkland Signiture Decaf Coffee the same processing as the Kirkland Signiture Columbian Decaf coffee

    Reply
  6. Pedro

    January 25, 2024 at 7:07 am

    It would be nice to know how much caffeine is still in the decaffeinated coffees. Especially for those who have severe problems with caffeine.

    Reply
    • Jimmy bean

      February 4, 2024 at 10:00 pm

      Starbucks uses methylene chloride method so I’m shocked that they are on the safe list here

      Reply
      • Anonymous

        March 2, 2024 at 4:57 pm

        not organic

        Reply
      • Zelle67

        April 8, 2024 at 5:06 pm

        If you click on Starbucks in the list of the safest decafs it takes you to an Amazon link for an instant Starbucks coffee!! Not the decaf you would imagine should be behind that link. This is fishy.

        Reply
  7. Bonita

    November 8, 2023 at 12:01 am

    I was surprised to find nescafe on the list but thank you very much.

    I have friends who work in specialty coffee and are very focused on freshness. I think nescafe would not be very fresh for sure and probably many others that are sold in super markets.

    I have heard that not fresh coffee can even cause cancer so I’m really glad the decaffination process is good but it may not be healthy still.

    Reply
    • Karen gadbury

      May 26, 2024 at 11:23 am

      How safe is food lions decaf coffee? It uses methylene chloride.

      Reply
  8. usps tracking

    November 6, 2023 at 8:09 am

    Is decaffeinated coffee completely caffeine-free, or does it still contain some caffeine?

    Reply
    • Anonymous

      April 8, 2024 at 5:27 pm

      There is still a very small amount

      Reply
  9. globle

    August 24, 2023 at 1:32 am

    I am overjoyed to have found out about this helpful website. It teaches me a lot of intriguing information about everything that’s going on, especially the subject matter of the article that was just before this one.

    Reply
  10. globle

    August 22, 2023 at 9:19 pm

    I don’t know how to thank you for this post.Really, I’m very pleased by this post. Whoever wrote it was a great person.thanks for telling us about this.Thank you for being ready to share what you know with us.

    Reply
  11. usps tracking

    August 22, 2023 at 2:27 am

    Thank you for having the greatest blog. I found it very beneficial.Continue to share such concepts in the future. Thank you for providing me with helpful information. I might need it!

    Reply
  12. DK

    March 14, 2023 at 8:04 pm

    Do any of these companies use TCE or another legacy solvent in place of methyl chloride?

    Reply
  13. Lagu Lagu

    December 6, 2021 at 4:49 am

    Great information, i love this food

    Reply
  14. Berd Connoly

    August 7, 2021 at 10:36 pm

    Nice explanation, I just found out the benefits of processed coffee to be very useful like this.

    Reply
  15. skribblio

    March 22, 2021 at 8:14 pm

    free fun entertainment games, join the game to have moments of relaxation, help increase energy all day long, work efficiently

    Reply
  16. skribblio

    March 22, 2021 at 8:14 pm

    Free fun entertainment games, join the game to have moments of relaxation, help increase energy all day long, work efficiently.

    Reply
  17. Cristen

    January 16, 2021 at 10:14 am

    Thank you this is very helpful!!

    (Can Lifeboost, Trim Healthy Mama and MLM company coffees be added to the next investigation?) ????

    Reply
  18. Bel tomlin

    January 16, 2021 at 9:29 am

    When you update can you add Sprouts bulk organic decaf french roast coffee? Thanks for all you do for our health.

    Reply
  19. J

    October 27, 2020 at 11:19 am

    On their site, they have Dunkin Donuts decaf medium roast as having methyl-chloride. 🙁

    Reply
    • H

      May 29, 2025 at 6:05 am

      Yes they do 🙁 I drank that my entire pregnancy based on other websites info. I think maybe there is no trace amount of the chemical but I’m throwing the rest out now and switching to Tim’s this pregnancy.

      Reply
  20. JM

    August 28, 2020 at 12:12 pm

    Do you have any thoughts on why there would be difference as between Starbucks, Kirkland Signature, and Seattle’s Best? All are sourced, roasted, and produced by Starbucks, in the same facilities as far as I’m aware.

    Reply
  21. fireboy and watergirl

    March 3, 2020 at 8:35 am

    They don’t use methyl chloride and there doesn’t seem to be contamination in the industry.

    Reply

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